天水地热资源开发策略

总结评价天水地热资源,依据目前世界不同的开发利用方向,分别对天水浅层地热能资源,中深层地热能资源的开发利用提出了具体方向和具体措施。     

Operando Ambient Pressure X-ray Photoelectron Spectroscopy Studies of Sodium–Oxygen Redox Reactions

Lower charge overpotential of sodium–oxygen (Na–O₂) batteries makes them a promising electrical storage technology. However, they have an undesirable discharge product, sodium carbonate (Na₂CO₃), which has widely been found in many previous studies. Whether and how the carbon components in the cathode are involved in the formation of Na₂CO₃ is still not well understood. Herein, an all solid-state Na–O₂ battery was constructed and its charge and discharge cycles were studied using ambient pressure X-ray photoelectron spectroscopy. The operando XPS results clearly demonstrate the formation of Na₂CO₃ on the cathode during the discharge cycle. A fraction of the carbonate formed can be cycled while charging the battery. Transformation of the carbon-based cathode to Na₂CO₃ is a potential cause of capacity fading of the Na–O₂ battery.     

Effect of ultrasound on the true flotation of lignite and its entrainment behavior

In this study, the ultrasound was fixed in the pulp zone of flotation cell and its effect on the true flotation of lignite was analyzed. Flotation results indicated that the simultaneous ultrasound treatment increased the concentrate yield and decreased the concentrate ash content. Screening analysis of flotation products revealed that the ultrasound could crush coarse coal to fine coal and scanning electron microscopy (SEM) tests indicated that the ultrasound could reduce the coverage of high-ash coal fines on the coarse particle surface. Thus, the flotation recovery of coarse lignite particle was increased. In addition, the true flotation and entrainment of ?0.074 mm fine particles were studied by the sink-float test and the method of Trahar. It was found the ultrasound significantly enhanced the true flotation of fine particles and improved the overall water recovery in lignite flotation.     

基于CFD的池式快堆多物理耦合分析方法研究

基于临界/次临界点堆中子动力学模型、燃料棒传热模型、热交换器和多孔介质等辅助热工水力模型，采用显式迭代和动态链接库技术（DLL），利用商用计算流体力学（CFD）程序FLUENT的用户自定义函数（UDF）实现中子动力学、燃料棒热传导等和快堆堆池冷却剂流动换热的耦合计算，开发池式快堆多物理耦合计算程序CFD/PF。采用CFD/PF开展小型自然循环铅铋快堆SNCLFR-10无保护超功率事故（UTOP）模拟，并与国际知名快堆多物理耦合分析程序SIMMR-III的计算结果开展Code-to-Code对比分析。研究结果表明:CFD/PF与SIMMER-III的分析结果吻合良好，耦合程序的开发取得了初步成功，可用于分析池式快堆堆池内的复杂三维流动和换热现象。      

Fe基非晶合金增强1060铝基多层复合材料的组织与性能

采用累积叠轧焊+中间退火法复合轧制1060Al/Fe基非晶多层铝合金复合板材。利用光学显微镜、扫描电镜、X-衍射分析仪以及拉伸试验机分析Al基复合材料的微观组织结构变化、断口形貌、物相组成以及力学性能。结果表明:Fe基非晶复合材料的增强体在300 ℃中间退火过程中发生部分晶化,在累积变形轧制过程中发生破碎,并随着变形道次的增加,破碎程度随之增大;复合板前6道次的累积轧制变形出现了明显的加工软化现象,并且随着变形道次的增加,其加工软化的效果愈明显;随着累积轧制变形道次增加,Al基复合材料的力学性能发生了明显的变化,第2道次轧制变形后屈服强度与抗拉强度达到了最大值为140 MPa和156 MPa,伸长率为5.53%,达到最佳综合性能。     

CO2对油田地下水环境中Q235钢和X70钢腐蚀行为的影响

为了探明辽河油田地下水环境中CO₂对Q235钢和X70管线钢的腐蚀规律,采用动电位极化技术及交流阻抗技术研究了不同CO₂浓度对该环境下两种钢腐蚀行为的影响,并利用光学显微镜对试样腐蚀界面进行表征。结果表明:随着CO₂浓度的增加,Q235和X70钢的交流阻抗图谱的半径均减小,腐蚀电流密度增大,腐蚀坑数量、深度和面积都增加,腐蚀敏感性增大。在低浓度CO₂环境下(CO₂含量为10%时),Q235钢的腐蚀敏感性比X70钢更高;而在高浓度CO₂环境下(CO₂含量为20%、40%、60%时),Q235钢的腐蚀速率反而较小,耐腐蚀性更好。     

Evaluation on Dorsey Method in Surface Tension Measurement of Solder Liquids Containing Surfactants

With the purpose of developing a feasible approach for measuring the surface tension of solders containing surfactants, the surface tension of Sn–3Ag–0.5Cu–xP solder alloys, with various drop sizes as well as different phosphorus (P) content, was evaluated using the Dorsey method based on the sessile drop test. The results show that the accuracy of the surface tension calculations depends on both of sessile drop size and the liquid metal composition. With a proper drop size, in the range of 4.5 mm to 5.3 mm in equivalent spherical diameters, the deviation of the surface tension calculation can be limited to 1.43 mN·m^?1 and 6.30 mN·m^?1 for SnAgCu and SnAgCu–P, respectively. The surface tension of SnAgCu–xP solder alloys decreases quickly to a minimum value when the P content reaches 0.5 wt% and subsequently increases slowly with the P content further increasing. The formation of a P-enriched surface layer and Sn₄P₃ intermetallic phases is regarded to be responsible for the decreasing and subsequent increasing of surface tension, respectively.     

Combined constant speed control method for a wind generator equipped with hydraulic energy storage

A wind generator equipped with hydraulic energy storage (WG‐HES) uses hydraulic transmission systems instead of gearbox transmissions, thus eliminating high‐power converters and reducing the tower‐top cabin weight. When there is no wind or the wind speed is extremely low, the pressured oil released by accumulators is used to drive a motor to operate at a constant speed, thereby generating constant‐frequency power. However, few studies have examined the constant speed control characteristics for generating electricity using only an accumulator group. In this study, a combined constant speed (CCS) proportional–integral–derivative (PID) control method based on “variable displacement and throttling” is proposed, which includes two closed loops and one regulating loop. First, a simulation model of the CCS PID control method for a variable motor was established in the Simcenter Amesim program. The influence of different PID parameters on the anti‐interference ability of the constant speed control of the motor was analyzed under a given load step. Then, we obtained the range of control parameter values and a set of optimal values. Second, the effectiveness of the CCS control method and the accuracy of the simulation results were verified on a 600‐kW WG‐HES system prototype. The results verified that the CCS control method has good anti‐interference ability and can meet the requirements of constant speed control for a variable motor under the best PID parameters. These results can provide a basis for developing control strategies for WG‐HESs when there is no wind or at low wind speeds.     

Ultra-stable K metal anode enabled by oxygen-rich carbon cloth

The K metal batteries are emerged as promising alternatives beyond commercialized Li-ion batteries. However, suppressing uncontrolled dendrite is crucial to the accomplishment of K metal batteries. Herein, an oxygen-rich treated carbon cloth (TCC) has been designed as the K plating host to guide K homogeneous nucleation and suppress the dendrite growth. Both density function theory calculations and experimental results demonstrate that abundant oxygen functional groups as K-philic sites on TCC can guide K nucleation and deposition homogeneously. As a result, the TCC electrode exhibits an ultra-long-life over 800 cycles at high current density of 3.0 mA·cm⁻² for 3.0 mA·h·cm⁻². Furthermore, the symmetrical cells can run stably for 2,000 h with low over-potential less than 20 mV at 1.0 mA·cm⁻² for 1.0 mA·h·cm⁻². Even at a higher current of 5.0 mA·cm⁻², the TCC electrode can still stably cycle for 1,400 h.